@article{5958, author = {J. P. R. Wells and M. Yamaga and N. Kodama and T. P. J. Han}, title = {Polarized laser spectroscopy and crystal-field analysis of Er3+ doped CaGdAlO4}, abstract = {A single Er3+ centre in CaGdAlO4:Er3+ has been identified to have C-4v symmetry from polarized laser selective excitation. This is consistent with isovalent substitution of the Er3+ ions for host crystal Gd3+ ions. Using both optical and infrared absorption and polarized laser excited fluorescence, 59 crystal-field energy levels and their wavefunction symmetries have been identified and used to perform comprehensive single electron crystal-field analyses for the Er3+ ion centre. For excitation of the F-4(9/2) multiplet, blue and green upconversion fluorescence is observed. Self-absorption dips recorded in upconversion excitation spectra are indicative of the presence of radiative energy transfer processes.}, year = {1999}, journal = {Journal of Physics-Condensed Matter}, volume = {11}, number = {39}, pages = {7545-7555}, month = {Oct 4}, isbn = {0953-8984}, doi = {10.1088/0953-8984/11/39/310}, language = {eng}, }