@article{7182, author = {S. Smolarek and A. M. Rijs and W. J. Buma and M. Drabbels}, title = {Absorption spectroscopy of adenine, 9-methyladenine, and 2-aminopurine in helium nanodroplets}, abstract = {High-resolution absorption spectra of adenine, 9-methyladenine and 2-aminopurine in helium nanodroplets have been recorded. In contrast to molecular beam experiments, large variations in linewidths are observed for adenine and 9-methyladenine. At the same time, the spectrum of 2-aminopurine remains sharp upon solvation in helium droplets. The line broadening observed for adenine and 9-methyladenine is attributed to a significant decrease of the lifetime of the (1)Lb(pi pi*) state and of (1)n pi* levels vibronically coupled to this state. The origin of the lifetime reduction is argued to be related to the increased accessibility of the (1)n pi*/L-1(b)(pi pi*) conical intersection upon solvation of these molecules in liquid helium.}, year = {2010}, journal = {Physical Chemistry Chemical Physics}, volume = {12}, number = {48}, pages = {15600-15606}, isbn = {1463-9076}, url = {://000284776700005 }, note = {ISI Document Delivery No.: 687KFTimes Cited: 0Cited Reference Count: 72}, language = {English}, }