@article{7200,
  author = {J. Oomens and J. D. Steill and T. H. Morton},
  title = {IR Spectra of Boron-Stabilized Anions in the Gas Phase},
  abstract = {Action spectroscopy of gaseous Me3BF- and Me2BCH2-, determined using IR multiple photon dissociation (IRMPD), exhibits experimental peak positions in good agreement with those predicted by anharmonic DFT calculations at the B3LYP/aug-cc-pVTZ level. Comparing spring constants among boron-carbon bonds and consideration of isoelectronic systems reveals that the anions have B-CH3 bonds a factor of 1.3-1.4 weaker than those in neutral trimethylboron, suggesting a greater role for hyperconjugation in 8(CH3)(3) than inferred from previous vibrational spectroscopic studies.},
  year = {2010},
  journal = {Inorganic Chemistry},
  volume = {49},
  number = {15},
  pages = {6781-6783},
  month = {Aug},
  isbn = {0020-1669},
  url = {<Go to ISI>://000280365300003 },
  note = {ISI Document Delivery No.: 631RLTimes Cited: 0Cited Reference Count: 28},
  language = {English},
}