@article{7474,
  author = {J. Oomens and T. H. Morton},
  title = {Aldehyde and Ketone Adducts of the Gaseous Trifluoromethyl Cation},
  abstract = {IR spectra of CF3+ adduct ions are reported for the first time using infrared multiple photon dissociation (IRMPD). Carbonyl stretches of ketone conjugate acids shift less than do those of ions containing C=OCF3+ groups. Carbonyl absorptions shift in proportion to the empirical softness of the corresponding neutrals. Anharmonic DFT fits band positions of C=OCF3+ stretches for aliphatic ions, but unscaled harmonic calculations match O-CF3 stretches more closely. Calculated O-CF3 bond orders increase with gas phase CF3+ affinities of the corresponding neutral carbonyl.},
  year = {2011},
  journal = {Organic Letters},
  volume = {13},
  number = {9},
  pages = {2176-2179},
  month = {May},
  isbn = {1523-7060},
  url = {DOI: 10.1021/ol200369m },
  note = {ISI Document Delivery No.: 755SMTimes Cited: 0Cited Reference Count: 34},
  language = {English},
}