@article{8142, author = {Q. Huang and Y. Lou and A. W. Kleyn and T. Zaharia and M. A. Gleeson}, title = {Collision-induced desorption of CO from Ru(0001) by hyperthermal argon and nitrogen}, abstract = {Collision-induced desorption of CO from Ru(0001) by hyperthermal (5–9 eV) effusive beams of Ar and N + N2 has been studied at a sample temperature of 400 K. Prompt desorption occurs with cross sections on the order of 4 Å2. Based on post-exposure thermal desorption measurements,   1/3 of the initial CO coverage cannot be desorbed by Ar on the time scale of the current experiments. In contrast, exposure to the mixed N + N2 beam appears to remove all CO from the irradiated region. This is attributed to a lowering of the CO binding energy by adsorbed N-atoms. While there is no evidence of a large influence of surface diffusion on the time scale of these exposure, desorption simulations suggest that local diffusion in the periphery of the exposed region influences the measured decay.}, year = {2016}, journal = {Surface Science}, volume = {650}, pages = {230 - 236}, month = {08/2016}, doi = {10.1016/j.susc.2015.12.016}, note = {The surface science of heterogeneous catalysis: In honor of Robert J. Madix}, language = {eng}, }