@article{8287,
  author = {A. N. Tabish and H. C. Patel and J. Schoonman and P. V. Aravind},
  title = {A detailed look into hydrogen electrochemical oxidation on ceria anodes},
  abstract = {Using the Nernst-Planck-Poisson model and a detailed reaction mechanism, we studied the hydrogen electrochemical oxidation on a ceria anode. Resistances caused by surface kinetics, and bulk transport of oxide-ion vacancies and electrons are computed individually to identify the dominant resistive process. The effect of operating conditions like temperature and gas-phase composition on the polarization resistance is evaluated and compared with the experimental data obtained by Electrochemical Impedance Spectroscopy (EIS). The rate-determining step is found to be the charge-transfer reaction in which hydrogen adsorbs at the surface oxide ions and forms hydroxyls along with the charge-transfer to adjacent cerium ions. Based on the rate-determining step, the exchange-current density is also calculated and validated with the experimental data.},
  year = {2018},
  journal = {Electrochimica Acta},
  volume = {283},
  pages = {789-797},
  month = {9/2018},
  doi = {10.1016/j.electacta.2018.05.058},
  language = {eng},
}