Preferential oxidation of CO in H2 on Cu and Cu/CeOx catalysts studied by in situ UV–Vis and mass spectrometry and DFT

TitlePreferential oxidation of CO in H2 on Cu and Cu/CeOx catalysts studied by in situ UV–Vis and mass spectrometry and DFT
Publication TypeJournal Article
Year of Publication2018
AuthorsY. Bu, S. Er, J.WH Niemantsverdriet, H.OA Fredriksson
JournalJournal of Catalysis
Volume357
Pagination176-187
Date Published01/2018
Abstract

Preferential oxidation of CO in H2 was studied by in situ ultraviolet–visible (UV–Vis) and mass spectrometry on flat model Cu and Cu/CeOx catalysts. The experimental findings were interpreted and compared with the results from density functional theory (DFT) calculations of the adsorption and activation energies for the essential reaction steps on Cu(1 1 1). It was found that oxidation of CO preferentially takes place on Cu(0) and that no significant H2 oxidation took place under any of the investigated conditions. The presence of CeOx accelerates Cu(0)-oxidation which leads to catalyst deactivation. In contrast, CeOx promotes the CO oxidation rate on catalysts that were already oxidized to CuOx. The coexistence of CO and H2 is important to sustain the stability of metallic Cu and thereby a high rate of CO2 formation. In pure CO/O2 gas, the metallic phase can only be maintained as long as full O2 conversion is reached. In pure H2/O2, Cu is always partly but never fully oxidized, suggesting that a passivating surface layer is formed. This is also the case for H2 rich gas mixtures with small amounts of CO and O2. The most active surface termination, Cu(0), can therefore not be maintained under the industrially most interesting reaction condition where full conversion of trace amounts of CO in H2 is required. DFT calculations predict that the dissociative H2 adsorption is a key limiting step for hydrogen oxidation on the Cu(1 1 1) surface, especially when the low sticking coefficient is taken into account. © 2017 The Authors

DOI10.1016/j.jcat.2017.11.014
Division

FP

Department

IMM

PID60699f0f174f34466d4696e87258271c
Alternate TitleJ. Catal.
LabelOA

Go back one page.