Resonant structure of low-energy H-3(+) dissociative recombination

TitleResonant structure of low-energy H-3(+) dissociative recombination
Publication TypeJournal Article
Year of Publication2011
AuthorsA. Petrignani, S. Altevogt, M.H Berg, D. Bing, M. Grieser, J. Hoffmann, B. Jordon-Thaden, C. Krantz, M.B Mendes, O. Novotny, S. Novotny, D.A Orlov, R. Repnow, T. Sorg, J. Stutzel, A. Wolf, H. Buhr, H. Kreckel, V. Kokoouline, C.H Greene
JournalPhysical Review A
Volume83
Number3
Pagination10
Date PublishedMar
Type of ArticleArticle
ISBN Number1050-2947
Accession NumberISI:000288445700004
KeywordsION, photodissociation, STORAGE-RING, TSR
Abstract

High-resolution dissociative recombination rate coefficients of rotationally cool and hot H-3(+) in the vibrational ground state have been measured with a 22-pole trap setup and a Penning ion source, respectively, at the ion storage-ring TSR. The experimental results are compared with theoretical calculations to explore the dependence of the rate coefficient on ion temperature and to study the contributions of different symmetries to probe the rich predicted resonance spectrum. The kinetic energy release was investigated by fragment imaging to derive internal temperatures of the stored parent ions under differing experimental conditions. Asystematic experimental assessment of heating effects is performed which, together with a survey of other recent storage-ring data, suggests that the present rotationally cool rate-coefficient measurement was performed at 380(-130)(+50) K and that this is the lowest rotational temperature so far realized in storage-ring rate-coefficient measurements on H-3(+). This partially supports the theoretical suggestion that temperatures higher than assumed in earlier experiments are the main cause for the large gap between the experimental and the theoretical rate coefficients. For the rotationally hot rate-coefficient measurement a temperature of below 3250 K is derived. From these higher-temperature results it is found that increasing the rotational ion temperature in the calculations cannot fully close the gap between the theoretical and the experimental rate coefficients.

URL<Go to ISI>://000288445700004
Division

GUTHz

Department

Molecular Dynamics

PID

486e2d405dabb4bc70a371f88ca2d72e

Alternate TitlePhys. Rev. A

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