Upcoming seminars

Seminars at DIFFER cover a wide range of topics and are held on Thursdays at 11.15 AM in the seminar room of the institute (unless otherwise stated). Seminars are open to everybody. If you are interested in visiting a DIFFER seminar or want to subscribe to our mailing list, please follow the instructions for external visitors.

List all past seminars organized at DIFFER

Irene Groot
March 28th 2019
11:15 to 12:15
The atomic-scale structure of a catalyst under reaction conditions determines its activity, selectivity, and stability. Recently it has become clear that essential differences can exist between the behavior of catalysts under industrial conditions (high pressure and temperature) and the (ultra)high vacuum conditions of traditional laboratory experiments. Differences in structure, composition, reaction mechanism, activity, and selectivity have been observed. These observations indicated the presence of the so-called pressure gap, and made it clear that meaningful results can only be obtained at high pressures and temperatures. However, most of the techniques traditionally used to study catalysts and their reactions were designed to operate under (ultra)high vacuum conditions. To bridge the pressure gap, the last years have seen a tremendous effort in designing new instruments and adapting existing ones to be able to investigate catalysts in situ under industrially relevant conditions. In this talk, I will give an overview of the in situ imaging techniques we use to study the structure of model catalysts under industrial conditions of atmospheric pressures and elevated temperatures. We have developed set-ups that combine an ultrahigh vacuum environment for model catalyst preparation and characterization with a high-pressure flow reactor cell, integrated with either a scanning tunneling microscope or an atomic force microscope. With these set-ups we are able to perform atomic-scale investigations of well-defined model catalysts under industrial conditions. Additionally, we combine the structural information from scanning probe microscopy with time-resolved mass spectrometry measurements on the gas mixture that leaves the reactor. In this way, we can correlate structural changes of the catalyst due to the gas composition with its catalytic performance. Furthermore, we use other in situ imaging techniques such as transmission electron microscopy, surface X-ray diffraction, and optical microscopy, all combined with mass spectrometry. This talk highlights a short overview of the instruments we developed and illustrates their performance with results obtained for different model catalysts and reactions. Results for reactions such as NO oxidation and hydrodesulfurization will be discussed.
Liesbeth Janssen
April 18th 2019
11:15 to 12:15
abstract will follow