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Crystal-growth and spectroscopy of Er3+ ions in calcium gallogermanate

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Abstract

This paper reports on the Czochralski growth of large single crystals of Er3+ doped Ca3Ga2Ge4O14 (CGGO) in radio frequency heated induction furnaces operating at 18 kHz. Crystals were successfully grown at concentrations of 0.005, 0.05, 0.5 and 5 mol% of the ErF3 dopant, and were of exceptionally good optical quality. Spectroscopic studies of the intra-4f shell absorption and fluorescence transitions of the Er3+ ions in this material were performed at 10 K, Measurements of the optical linewidths show no signs of concentration broadening up to 5 mol%, a feature attributable to the intrinsic compositional disorder of the crystal. We have identified 67 crystal-field levels of the C-2 symmetry site available for occupation by a trivalent rare-earth ion and observe strong up-conversion fluorescence for excitation (both resonant and non-resonant) of the absorption transitions from the ground state to the F-4(9/2) multiplet. Prominent self-absorption dips observed in excitation spectra recorded whilst monitoring up-converted fluorescence, demonstrate the importance of radiative energy transfer at high concentrations. (C) 2000 Elsevier Science B.V. All rights reserved.

Year of Publication
2000
Journal
Journal of Crystal Growth
Volume
217
Number
3
Number of Pages
302-310
Date Published
Aug
ISBN Number
0022-0248
DOI
PId
100a19a4f64f4d7e1f4271d641df21ce
Journal Article
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