Crystal-growth and spectroscopy of Er3+ ions in calcium gallogermanate
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Author | |
Abstract |
This paper reports on the Czochralski growth of large single crystals of Er3+ doped Ca3Ga2Ge4O14 (CGGO) in radio frequency heated induction furnaces operating at 18 kHz. Crystals were successfully grown at concentrations of 0.005, 0.05, 0.5 and 5 mol% of the ErF3 dopant, and were of exceptionally good optical quality. Spectroscopic studies of the intra-4f shell absorption and fluorescence transitions of the Er3+ ions in this material were performed at 10 K, Measurements of the optical linewidths show no signs of concentration broadening up to 5 mol%, a feature attributable to the intrinsic compositional disorder of the crystal. We have identified 67 crystal-field levels of the C-2 symmetry site available for occupation by a trivalent rare-earth ion and observe strong up-conversion fluorescence for excitation (both resonant and non-resonant) of the absorption transitions from the ground state to the F-4(9/2) multiplet. Prominent self-absorption dips observed in excitation spectra recorded whilst monitoring up-converted fluorescence, demonstrate the importance of radiative energy transfer at high concentrations. (C) 2000 Elsevier Science B.V. All rights reserved. |
Year of Publication |
2000
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Journal |
Journal of Crystal Growth
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Volume |
217
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Number |
3
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Number of Pages |
302-310
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Date Published |
Aug
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ISBN Number |
0022-0248
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DOI | |
PId |
100a19a4f64f4d7e1f4271d641df21ce
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Journal Article
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