DIFFER
DIFFER Publication
Label | Value |
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Author | |
Abstract |
We characterize the low-temperature dynamics of CO intercalated in C-60 using NMR spectroscopy. CO in C-60 is found to be dynamically inhomogeneous below 30 K: The (CO)-C-13 line shapes reflect a dynamic disorder to static disorder transition, with only quantum tunneling among equivalent orientations in a local S-6 symmetry potential remaining. The increased hindrance of the CO motion cannot be reconciled with common expectations of a homogeneous, thermally activated jumplike reorientation process, but is well accounted for in a model of orientational pinning due to asymmetric distortions of the cage potential. (C) 2000 American Institute of Physics. [S0021-9606(00)70837-3]. |
Year of Publication |
2000
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Journal |
Journal of Chemical Physics
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Volume |
113
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Number |
13
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Number of Pages |
5141-5144
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Date Published |
Oct 1
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ISBN Number |
0021-9606
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DOI | |
PId |
7567967baf7baef2049b4ff46b981b11
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Journal Article
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