DIFFER
DIFFER Publication
Label | Value |
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Author | |
Abstract |
We report the first IR spectroscopic observation of carboxylate stretching modes in free space, i.e., in the complete absence of solvent or counterions. Gas-phase spectra of a series of benzoate anions have been recorded and compared to condensed-phase spectra, revealing the profound influence of the environment on the symmetric and antisymmetric carboxylate stretch modes. |
Year of Publication |
2008
|
Journal |
Journal of Physical Chemistry A
|
Volume |
112
|
Number |
15
|
Number of Pages |
3281-3283
|
Date Published |
Apr
|
Type of Article |
Letter
|
ISBN Number |
1089-5639
|
Accession Number |
ISI:000254883800001
|
URL | |
PId |
e671716dbbdff385feb78b20fe8ecac7
|
Alternate Journal |
J. Phys. Chem. A
|
Journal Article
|
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