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Activation of Molecular Oxygen by Anionic Gold Clusters
| Author | |
| Abstract |
A golden opportunity: Molecular oxygen is found to be converted into a superoxo (O2−) species upon complexation to gold-cluster anions containing an even number of Au atoms. Vibrational spectra (see scheme) reveal small variations in the extent of O[BOND]O bond activation dependent upon the electron affinity of the parent cluster. |
| Year of Publication |
2012
|
| Journal |
Angewandte Chemie International Edition
|
| Volume |
51
|
| Number |
18
|
| Number of Pages |
4444–4447
|
| Publisher |
WILEY-VCH Verlag
|
| DOI |
10.1002/anie.201108958
|
| PId |
19ec87f6fc6100cf3c035b2f634f1c7d
|
| Alternate Journal |
Angew. Chem. Int. Ed.
|
Journal Article
|
|
| Download citation |